• 文献标题:   High performance non-enzymatic graphene-based glucose fuel cell operated under moderate temperatures and a neutral solution
  • 文献类型:   Article
  • 作  者:   SU CH, SUN CL, PENG SY, WU JJ, HUANG YH, LIAO YC
  • 作者关键词:   glucose fuel cell, nonenzyme, platinumpalladium nanoparticle, graphene, nitrogendoped graphene oxide nanoribbon
  • 出版物名称:   JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
  • ISSN:   1876-1070 EI 1876-1089
  • 通讯作者地址:   Natl Taiwan Univ
  • 被引频次:   4
  • DOI:   10.1016/j.jtice.2018.09.034
  • 出版年:   2019

▎ 摘  要

In this study, a non-enzyme glucose fuel cell is assembled and shows high energy density in neutral solution at moderate temperature. The anodic material, graphene sheets grafted with platinum and palladium (PtPd/G), is prepared by polyol method to oxidize glucose. The cathode material, nitrogen-doped graphene oxide nanoribbons (NGONR) is prepared by a microwave process, and shows great oxygen reduction capability in neutral cerebrospinal fluid (CSF) solution. After cell assembly, test results show that the performance of the glucose fuel cell is significantly affected by oxygen concentration, glucose concentration and operating temperature. Compared with the enzyme glucose fuel cell, the non-enzyme glucose fuel cell can generate power not only at room or human body temperatures, but within a temperature range from 5 to 80 degrees C. The cell power density increases with increasing operating temperature. The assembled fuel cell can produce a maximum power density of 24.9 mu W/cm(2) in a neutral 10 mM CSF and 8 mM glucose solution at 80 degrees C with an oxygen purge flow. (C)2018 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.