• 文献标题:   Mechanistic insights into the reactive radicals-assisted degradation of sulfamethoxazole via calcium peroxide activation by manganese-incorporated iron oxide-graphene nanocomposite: Formation of radicals and degradation pathway
  • 文献类型:   Article
  • 作  者:   AMINA, SI XY, WU K, SI YB, YOUSAF B
  • 作者关键词:   calcium peroxide cao2, sulfamethoxazole smx, rgoaptmsfmbo nanocomposite, free radical specie, modified fenton system, catalytic oxidation
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Anhui Agr Univ
  • 被引频次:   2
  • DOI:   10.1016/j.cej.2019.123360
  • 出版年:   2020

▎ 摘  要

In this study, fabrication of manganese-incorporated iron oxide-graphene nanocomposite (rGO-FMBO) was reported for the efficient activation of CaO2 and generation of reactive radicals for the degradation of sulfamethoxazole (SMX). The effects of different systems, catalyst dosage, oxidant dosage, different pH and different reaction time on the degradation of SMX by rGO-APTMS-FMBO/CaO2 as well as the production of free radicals were also studied. Electron paramagnetic resonance (EPR) technique was used to detect and identify the radical species in this oxidation system and these radicals were further confirmed by scavenging studies with the addition of isopropanol (IPA) and methyl viologen (MV2+). The results indicated that the CaO2 could be activated by rGO-APTMS-FMBO efficiently for the effective degradation of SMX at neutral pH (P