• 文献标题:   One-spot synthesis of FeOOH/rGO composites by ferrous-ion-induced self-assembly of graphene oxides with different degrees of oxidation
  • 文献类型:   Article
  • 作  者:   HU Y, YANG QY, GU YY
  • 作者关键词:  
  • 出版物名称:   PLOS ONE
  • ISSN:   1932-6203
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1371/journal.pone.0246386
  • 出版年:   2021

▎ 摘  要

In this study, graphene oxide sheets with different oxidation degrees were reduced by ferrous ion for coating FeOOH nano particles on reduced graphene oxide (rGO) matrix to synthesize FeOOH/rGO composites. The effect of the degree of oxidation on the morphology and chemical structure of FeOOH/rGO was studied using scanning electron microscopy, Raman spectroscopy, thermogravimetric analysis, and Brunauer-Emmett-Teller surface area analysis. The particle size of FeOOH crystallites was approximately 100 nm, and they were distributed uniformly on the surface and in the pores of FeOOH/rGO. FeOOH/rGO prepared with mildly oxidized graphite had fewer defects, higher specific surface area, and higher FeOOH content than FeOOH/rGO prepared with highly oxidized graphite. These features resulted in better electrochemical properties, such as larger specific capacitance and lower charge transfer resistance.