• 文献标题:   Structural, optical and terahertz properties of graphene-mesoporous silicon nanocomposites
  • 文献类型:   Article
  • 作  者:   FANDIO DJ, SAUZE S, BOUCHERIF A, ARES R, MORRIS D
  • 作者关键词:  
  • 出版物名称:   NANOSCALE ADVANCES
  • ISSN:   2516-0230
  • 通讯作者地址:   Univ Sherbrooke
  • 被引频次:   2
  • DOI:   10.1039/c9na00502a
  • 出版年:   2020

▎ 摘  要

We investigate the structural, optical and terahertz properties of graphene-mesoporous silicon nanocomposites using Raman, terahertz time-domain and photoluminescence spectroscopy. The nanocomposites consist of a free-standing mesoporous silicon membrane with its external and pore surfaces coated with few-layer graphene. Results show a stabilization of the porous silicon morphology by the graphene coating. The terahertz refractive index and absorption coefficient were found to increase with graphene deposition temperature. Four bands in the 1.79-2.2 eV range emerge from the PL spectra of the nanocomposites. The broad bands centered at 1.79 eV and 1.96 eV were demonstrated to originate from Si nanocrystallites of different sizes. The narrower bands at 2.11 eV and 2.14 eV could be related to a thin SiC film at the Si/C interface.