• 文献标题:   Sensitive determination of thymol based on CeO2 nanoparticle-decorated graphene hybrid film
  • 文献类型:   Article
  • 作  者:   ZHAO XJ, DU YL, YE WC, LU DB, XIA XH, WANG CM
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   24
  • DOI:   10.1039/c3nj01059g
  • 出版年:   2013

▎ 摘  要

A novel thymol electrochemical sensor based on a CeO2 nanoparticle-decorated graphene hybrid was introduced. The hybrid was characterized by X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. The electrochemical behavior of thymol on the CeO2/graphene modified glassy carbon electrode was investigated in pH 7.0 phosphate buffer solution by cyclic voltammetry and differential pulse voltammetry. Compared with the bare glassy carbon electrode, the proposed electrode showed improved analytical performance characteristics in catalytic oxidation of thymol. Under the selective conditions, the modified electrode showed a linear voltammetric response for the thymol within a concentration range of 1.0 x 10(-7) to 1.8 x 10(-5) mol L-1, and a value of 5.0 x 10(-8) mol L-1 was calculated for the detection limit (S/N = 3). Furthermore, good selectivity with high sensitivity was obtained for the determination of thymol in real samples.