• 文献标题:   Iron oxide nanoparticles wrapped in graphene aerogel composite: Fabrication and application in electro-fenton at a Wide pH
  • 文献类型:   Article
  • 作  者:   CAO XL, JIANG DM, HUANG MY, PAN J, LIN JJ, CHAN W
  • 作者关键词:   alphafe2o3/ga, ef, rhb, wide ph range, hydrogen peroxide
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Chongqing Three Gorges Univ
  • 被引频次:   3
  • DOI:   10.1016/j.colsurfa.2019.124269
  • 出版年:   2020

▎ 摘  要

A novel composite material of alpha-Fe2O3 nanoparticles wrapped in grape aerogel (alpha-Fe2O3/GA) was successfully fabricated and proposed for the electro-Fenton (EF) system. The alpha-Fe2O3/GA, which prepared by the natural drying method, presented characteristics of a porous structure of graphene sheets with alpha-Fe2O3 nanoparticles uniformly dispersed. Efficient electro-catalytic performance was exhibited when applied to degrade Rhodamine B (RhB). The results showed that the degradation rate reached 99% after 30 min, which was about 1.1 times higher than that of graphene aerogel (GA). Meanwhile, the chemical oxygen demand (COD) elimination rates up to 82% in the reaction, and the corresponding energy consumption is 90% of that with GA. Furthermore, it's worth noting that the alpha-Fe2O3/GA presented low iron leaching (<,2.3 mg/l) even in an acidic medium, without significant decrease in catalytic activity after six cycles. Besides, alpha-Fe2O3/GA retained an efficient degradation efficiency at a wide pH range. Therefore, alpha-Fe2O3/GA was used as a candidate cathode material for treatment of organic wastewater by EF system.