• 文献标题:   Graphite Oxide and Graphene Nanoribbons Reduction with Hydrogen Iodide
  • 文献类型:   Article
  • 作  者:   CATALDO F, URSINI O, ANGELINI G
  • 作者关键词:   graphite oxide, graphene nanoribbon, hydrogen iodide, hydroiodic acid, hydrazine, ftir, tgadtg
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X
  • 通讯作者地址:   Lupi Chem Res
  • 被引频次:   18
  • DOI:   10.1080/1536383X.2010.481064
  • 出版年:   2011

▎ 摘  要

It is shown that both graphite oxide (GO) and oxidized graphene nanoribbons (OGN) can be safely reduced by using hydrogen iodide (hydroiodic acid). FT-IR spectroscopy and TGA-DTG were used to show that HI 67% is able to lead to a complete reduction of GO while HI 57% is less effective. In terms of FT-IR spectroscopy and thermal analysis, the HI-reduced GO is almost identical to the N2H4-reduced GO. Hydrogen iodide 57% is in any case effective in reducing OGN. Since hydrazine is extremely toxic and explosive when anhydrous, it is suggested to use HI (preferably at 67% concentration) as alternative, safe and effective reducing agent.