• 文献标题:   3D SnO2/sulfonated graphene composites with interpenetrating porous structure as anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   WU BZ, LI GH, LIU FQ
  • 作者关键词:   sno2, sulfonated graphene, porous structure, anode material
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   4
  • DOI:   10.1016/j.ijhydene.2017.07.089
  • 出版年:   2017

▎ 摘  要

Combine SnO2 nanoparticles with some conductive carbonaceous materials has been regarded as one of the most effective strategies to solve the problems of poor conductivity and volume change. In this work, a SnO2/sulfonated graphene composite with 3D interpenetrating porous structure (3D SnO2/SG) was synthesized. The elaborate designed 3D SG structure not only generates an excellent electronic conductivity, but also buffers the volume expansion of the SnO2 particles. As a result, the desirable 3D possesses enhanced performance when used as anode material in lithium battery. For example, the electro-chemical results showed that the 3D SnO2/SG presents a high reversible specific capacity (928.5 mA h g(-1) at the current density of 200 mA g(-1). Even after 120 cycles, the specific capacity of 679.7 mA h g(-1) (at the current density of 400 mA g(-1)) are still maintained. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.