• 文献标题:   Platinum nanoparticles anchored on graphene oxide-dispersed pristine carbon nanotube supports: High-performance electrocatalysts toward methanol electrooxidation
  • 文献类型:   Article
  • 作  者:   ZHANG X, ZHANG JF, HUANG HJ, JIANG QG, WU YP
  • 作者关键词:   platinum nanoparticle, graphene, pristine carbon nanotube, methanol oxidation, electrocatalyst
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Hohai Univ
  • 被引频次:   11
  • DOI:   10.1016/j.electacta.2017.11.142
  • 出版年:   2017

▎ 摘  要

Herein, the growth of ultrafine Pt nanoparticles on graphene oxide-dispersed pristine carbon nanotube (G-PCNT) supports has been achieved by a convenient and scalable approach. Remarkably, the resulting Pt/G-PCNT hybrid possesses a series of distinct structural advantages, such as cross-linked porous framework, large specific surface area, low-defect CNT skeletons, uniform Pt dispersion, and excellent electron conductivity, which lead to the strong synergetic coupling effects that are very beneficial for methanol oxidation reaction. As a consequence, exceptional catalytic activity, good electrochemical stability, and strong poison tolerance are observed for the obtained Pt/G-PCNT catalyst, all of which are evidently superior to those for conventional Pt/carbon black, Pt/acid-treated CNTs, and Pt/graphene catalysts. (C) 2017 Elsevier Ltd. All rights reserved.