• 文献标题:   The crystallization behaviors and rheological properties of polypropylene/graphene nanocomposites: The role of surface structure of reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   CHEN Y, YIN Q, ZHANG XM, XUE XD, JIA HB
  • 作者关键词:   reduced graphene oxide, surface structure, crystallization behavior, rheological propertie
  • 出版物名称:   THERMOCHIMICA ACTA
  • ISSN:   0040-6031 EI 1872-762X
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1016/j.tca.2018.01.021
  • 出版年:   2018

▎ 摘  要

In this work, polypropylene (PP)/reduced graphene oxide (RGO) with various surface structures were fabricated. The crystallization behaviors and non-isothermal crystallization kinetics of PP/RGO nanocomposites were thoroughly studied. The results showed that the crystallization peak temperature, crystallization rate as well as crystallization degree of PP/RGO nanocomposites were greatly enhanced with the increase of reduced extent of RGO. Non-isothermal crystallization kinetics displayed that RGO with high reduction extent exhibited strong nucleation ability, which could decrease crystallization activation energy and accelerate the crystallization process. The rheological behaviors of the PP/RGO nanocomposites were also investigated. It was found that the non-newtonian behaviors of PP nanocomposites became stronger with the increase of reduction extent of RGO.