• 文献标题:   Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes
  • 文献类型:   Article
  • 作  者:   ZHANG R, CHEN XR, CHEN X, CHENG XB, ZHANG XQ, YAN C, ZHANG Q
  • 作者关键词:   lithium dendrite, lithium metal anode, nitrogendoped graphene, nucleation growth, rechargeable batterie
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   285
  • DOI:   10.1002/anie.201702099
  • 出版年:   2017

▎ 摘  要

Lithium (Li) metal is the most promising electrode for next-generation rechargeable batteries. However, the challenges induced by Li dendrites on a working Li metal anode hinder the practical applications of Li metal batteries. Herein, nitrogen (N) doped graphene was adopted as the Li plating matrix to regulate Li metal nucleation and suppress dendrite growth. The N-containing functional groups, such as pyridinic and pyrrolic nitrogen in the N-doped graphene, are lithiophilic, which guide the metallic Li nucleation causing the metal to distribute uniformly on the anode surface. As a result, the N-doped graphene modified Li metal anode exhibits a dendritefree morphology during repeated Li plating and demonstrates a high Coulombic efficiency of 98% for near 200 cycles.