• 文献标题:   Amperometric sensing of hydrazine using a magnetic glassy carbon electrode modified with a ternary composite prepared from Prussian blue, Fe3O4 nanoparticles, and reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   GUO WH, MA JG, CAO XH, TONG XL, LIU F, LIU YH, ZHANG ZB, LIU SB
  • 作者关键词:   magnetite nanoparticle, reduced graphene oxide, prussian blue, hydrazine, electrocatalysi, magnetic glassy carbon electrode, modified electrode
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   East China Univ Technol
  • 被引频次:   4
  • DOI:   10.1007/s00604-017-2289-x
  • 出版年:   2017

▎ 摘  要

A magnetic glassy carbon electrode (mGCE) was modified with a ternary composite prepared from Prussian blue (PB), magnetite (Fe3O4) nanoparticles, and reduced graphene oxide (rGO) in order to obtain an amperometric sensor for hydrazine. The utilization of Fe3O4 facilitates the magnetic immobilization and separation of sensing material, while the use of rGO enhances sensitivity. The surface coverage and the stability of the PB on the modified electrode were considerably improved. The electro-oxidative response to hydrazine was investigated with this modified mGCE using cyclic voltammetry and amperometric. The sensor, typically operated at a voltage of 0.2 V (vs. SCE), displays superior response hydrazine, with a response time of 4 s, a sensitivity of 97.73 mu A mu M-1 cm(-2) and a 13.7 nM detection limit.