• 文献标题:   Kinetic, equilibrium, and thermodynamic performance of sulfonamides adsorption onto graphene
  • 文献类型:   Article
  • 作  者:   ZHUANG ST, ZHU X, WANG JL
  • 作者关键词:   graphene, antibiotic, sulfamethazine, adsorption, kinetic
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   1
  • DOI:   10.1007/s11356-018-3368-1
  • 出版年:   2018

▎ 摘  要

With the extensive production and consumption of sulfonamide antibiotics, their existence in aquatic environments has received increasing attention due to their acute and chronic toxic effects. In this study, graphene was characterized and applied for sulfamethazine (SMT) removal from aqueous solution. The effect of the contact time (0-1440min), initial concentration (2-100mgL(-1)), and temperature (298-318K), as well as pH (2-9) and ionic strength (0-0.2M NaNO3), have been examined. The maximum adsorption capacity was calculated to be 104.9mgg(-1) using the Langmuir model. The endothermic adsorption process (oH=10.940kJmol(-1)) was pH- and temperature-dependent, and the adsorption data fitted well with the Langmuir isothermal and the pseudo second-order kinetic models. Additionally, ionic strength (0.01 to 0.2M NaNO3) had no obvious influence on SMT adsorption by graphene. Ultimately, graphene proved to be an effective adsorbent for sulfonamide antibiotics removal from aqueous solutions.