• 文献标题:   Self-assembling porous network nanostructure 7-aminoindole decorated reduced graphene oxide for high-performance asymmetric supercapacitor
  • 文献类型:   Article
  • 作  者:   ZHANG WY, SUN CY, XU YG, KANG HW, YANG BC, LIU HL, LI ZK
  • 作者关键词:   7airgo composite, mesoporous nanostructure, synergetic enhancement effect, energy storage, asymmetric supercapacitor
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Huanghe Sci Technol Coll
  • 被引频次:   0
  • DOI:   10.1016/j.jallcom.2020.155412
  • 出版年:   2020

▎ 摘  要

The design and preparation of novel green and efficient energy storage electrode materials is a crucial way to solve the problem of intermittent energy storage of renewable energy. In this paper, the composite electrode materials of rGO decorated by organic 7-aminoindole (7-Ai) molecule with the characteristics of fast reversible redox kinetics are synthesized successfully. The modified 7-AirGOs composites can not only produce extra pseudocapacitance, which greatly improve the specific capacitance, but also form a stable mesoporous nanostructure to facilitate the diffusion and transport of ions. By investigating the influence of 7-Ai molecule content on the electrochemical performance of the composite electrodes, the 7-AirGO1 electrode is chosen as the optimum electrode, which exhibits a high specific capacitance of 425.73 F g(-1) at 0.5 A g(-1) and an excellent rate capability with the current density increased to 20 A g(-1). Furthermore, the asymmetric supercapacitor assembled by the 7-AirGO1 and AC as positive and negative electrode respectively delivers an energy density of 14.60 W h kg(-1) and a power density up to 10,500 W kg(-1), as well as a cycling stability with a capacitance retention of 97.98% at a current density of 4 A g(-1) for over 20,000 cycles. These results indicate that rGO-aminoindole composites are of great potential in flexible and wearable micro energy storage devices. (C) 2020 Elsevier B.V. All rights reserved.