• 文献标题:   Voltammetric detection of catechol in real samples using MnO2 nanorods-graphene oxide nanocomposite modified electrode
  • 文献类型:   Article
  • 作  者:   KARAMIKOLMOTI P, BEITOLLAHI H, MODIRI S
  • 作者关键词:   e, electrochemical sensing, catechol, voltammetry, mno2 nrsgo nanocomposite
  • 出版物名称:   JOURNAL OF FOOD MEASUREMENT CHARACTERIZATION
  • ISSN:   2193-4126 EI 2193-4134
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s11694-022-01692-9 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

The current effort benefited from a simple hydrothermal production protocol to fabricate a nanocomposite using graphene oxide nanosheets anchored with manganese dioxide nanorods (MnO2 NRs-GO) that was applied to construct a sensitive electrochemical catechol sensing system. As-produced nanocomposite was characterized by Field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and Fourier transformed-infrared spectroscopy (FT-IR), which was then drop-casted on glassy carbon electrode (MnO2 NRs-GO/GCE) for sensor application. The MnO2 NRs-GO/GCE showed remarkable electrocatalytic capacity for the redox reaction of catechol, with minimized redox overpotentials and boosted voltammetric peak currents. As-fabricated sensor displayed an admirable electrocatalytic behavior to catechol, with a narrow limit of detection (0.02 mu M), a broad linear range (0.5-400.0 mu M) and an impressive sensitivity (0.0503 mu A/mu M). The MnO2 NRs-GO/GCE was also successful in sensing catechol in real specimens, with appreciable recovery rates.