• 文献标题:   Metal-Free Sustainable Synthesis of Amides via Oxidative Amidation Using Graphene Oxide as Carbocatalyst in Aqueous Medium
  • 文献类型:   Article
  • 作  者:   DANDIA A, PARIHAR S, SAINI P, RATHORE KS, PAREWA V
  • 作者关键词:   carbocatalyst, oxidative amidation, metalfree synthesi
  • 出版物名称:   CATALYSIS LETTERS
  • ISSN:   1011-372X EI 1572-879X
  • 通讯作者地址:   Univ Rajasthan
  • 被引频次:   1
  • DOI:   10.1007/s10562-019-02878-5
  • 出版年:   2019

▎ 摘  要

We describe an efficient, clean and metal-free procedure for the synthesis of amides via oxidative amidation of aldehydes with anilines using graphene oxide (GO) as a recyclable catalyst and KBrO3 as a mild oxidant in aqueous medium under microwave irradiation. GO nanosheets were prepared and characterized by XRD, TEM, SEM, and FT-IR, analyses. GO showed high compatibility with KBrO3 in water and offered high TOF value (1.30 x 10(-3) mol g(-1) min(-1)). GO oxygen functionalities catalyze the oxidative amidation effectively in mild condition with high recyclability. A plausible mechanism was proposed by the isolating the intermediate.