• 文献标题:   Controlled fabrication of well-dispersed AgPd nanoclusters supported on reduced graphene oxide with highly enhanced catalytic properties towards 4-nitrophenol reduction
  • 文献类型:   Article
  • 作  者:   ZHU XY, LV ZS, FENG JJ, YUAN PX, ZHANG L, CHEN JR, WANG AJ
  • 作者关键词:   bimetallic alloyed nanocluster, 4nitrophenol, reduced graphene oxide, catalysi
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   41
  • DOI:   10.1016/j.jcis.2018.01.047
  • 出版年:   2018

▎ 摘  要

To realize the efficient and complete removal of organic pollutants in waste water, it is highly urgent for scalable synthesis of either self-supported bimetallic nanocatalysts or anchored on carbon-based materials. In this study, a simple one-pot coreduction method was developed for preparing well-dispersed AgPd alloyed nanoclusters uniformly dispersed on reduced graphene oxide (AgPd NCs/rGO) at room temperature by utilizing 5-azacytosine as the capping agent. The nanocomposites were characterized by a set of physical characterizations. The formation mechanism and catalytic mechanism were discussed in some details. Moreover, the prepared AgPd NCs/rGO exhibited dramatically increased catalytic properties towards the reduction of 4-nitrophenol (4-NP) in the presence of NaBH4 when compared to commercial Pd/C (20 wt.%). (C) 2018 Elsevier Inc. All rights reserved.