• 文献标题:   Metal to insulator transition in conducting polyaniline/graphene oxide composites
  • 文献类型:   Article
  • 作  者:   NETI E, SAKELLIS E, PAPATHANASSIOU AN, VITORATOS E, SAKKOPOULOS S
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Univ Athens
  • 被引频次:   2
  • DOI:   10.1063/1.5089814
  • 出版年:   2019

▎ 摘  要

Broadband dielectric spectroscopy measurements of polyaniline/graphene oxide composites were conducted for an as-prepared and a thermally annealed specimen, respectively, from 15 K to room temperature. The electrical conductivity values of the annealed composite display a very modest rise denoting the important contributions of the graphene oxide component to achieving electrical stability of the polymer. Patterns of the dc conductivity as a function of temperature also reveal a metal to insulator transition at around 75 K. The transition is dominated by two key factors: temperature and annealing process. Metal-like and insulating features are subsequently detected, as well, and accordingly described to provide a qualitative inspection of the charge transfer mechanisms involved. Published under license by AIP Publishing.