• 文献标题:   Effect of Temperature on Carbon-coated Graphene for Lithium-ion Batteries with Improved Performance
  • 文献类型:   Article
  • 作  者:   ZHU BY, WANG YC, WANG HB, NI JF, GAO LJ
  • 作者关键词:  
  • 出版物名称:   CHEMISTRY LETTERS
  • ISSN:   0366-7022 EI 1348-0715
  • 通讯作者地址:   Soochow Univ
  • 被引频次:   2
  • DOI:   10.1246/cl.130261
  • 出版年:   2013

▎ 摘  要

Carbon-coated graphene was synthesized through pyrolysis of a polyaniline-graphite oxide (PANI-GO) precursor by annealing in an Ar and H-2 atmosphere at various temperatures. X-ray diffraction, field-emission scanning and high-resolution transmission electron microscopies, X-ray photoelectron spectroscopy, Raman spectra, and thermogravimetric analysis were used to characterize the pyrolyzed PANI-GO at different temperatures. The PANI on the graphene at temperatures above 650 degrees C was completely converted into a nanocarbon film. Galvanostatic charge-discharge tests revealed that PANI-GO-800 exhibited improved rate and cycle capabilities over that of graphene due to the increased conductivity in the out-of-plane direction.