• 文献标题:   ZnO nanoparticles' decorated reduced-graphene oxide: Easy synthesis, unique polarization behavior, and ionic conductivity
  • 文献类型:   Article
  • 作  者:   JAMMULA RK, SRIKANTH VVSS, HAZRA BK, SRINATH S
  • 作者关键词:   nanocomposite, interface, dielectric, functional, surface, zno, graphene
  • 出版物名称:   MATERIALS DESIGN
  • ISSN:   0264-1275 EI 1873-4197
  • 通讯作者地址:   Univ Hyderabad
  • 被引频次:   7
  • DOI:   10.1016/j.matdes.2016.08.001
  • 出版年:   2016

▎ 摘  要

This work's focus is on the easy synthesis, elucidation of material characteristics and unique polarization behavior of ZnO nanoparticles' decorated r-GO. An optimized molecular-level mixing technique is used to synthesize ZnO decorated r-GO. The composite is found to exhibit high remnant polarization while its ionic conductivity follows the Arrhenius law. The observed polarization behavior is attributed to the lattice parameter disorder in ZnO combined with the presence of an appropriate number of functional groups in the composites. Moreover, a slight increase in r-GO content in the composites can increase the remnant polarization by one order of magnitude (i.e., from 0.062 mu C/cm(2) to 0232 mu C/cm(2)) under the influence of an external electric field (similar to 1.6 kV/cm). Experimental observations clearly indicate that the functionalized r-GO plays an important role (i.e., it facilitates easy dipolar alignment and reorientation) in polarization and increasing the number of stable polarization states with respect to the applied field direction. (C) 2016 Elsevier Ltd. All rights reserved.