• 文献标题:   A method for the production of reduced graphene oxide using benzylamine as a reducing and stabilizing agent and its subsequent decoration with Ag nanoparticles for enzymeless hydrogen peroxide detection
  • 文献类型:   Article
  • 作  者:   LIU S, TIAN JQ, WANG L, SUN XP
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   259
  • DOI:   10.1016/j.carbon.2011.03.036
  • 出版年:   2011

▎ 摘  要

A stable aqueous dispersion of reduced graphene oxide (rGO) has been prepared by the chemical reduction of graphene oxide with the use of benzylamine as a reducing and stabilizing agent. Raman spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the resulting rGO. The rGO could be decorated with Ag nanoparticles (AgNPs) by direct adsorption of preformed, negatively-charged AgNPs. It was found that the resulting hybrid exhibits good catalytic activity toward the reduction of hydrogen peroxide, leading to an enzymeless sensor with a fast amperometric response time of less than 2 s. The linear detection range is estimated to be from 100 mu M to 100 mM (r = 0.999), and the detection limit is estimated to be 31.3 mu M at a signal-to-noise ratio of 3. (C) 2011 Elsevier Ltd. All rights reserved.