• 文献标题:   Gram-scale production of graphene based on solvothermal synthesis and sonication
  • 文献类型:   Article
  • 作  者:   CHOUCAIR M, THORDARSON P, STRIDE JA
  • 作者关键词:  
  • 出版物名称:   NATURE NANOTECHNOLOGY
  • ISSN:   1748-3387
  • 通讯作者地址:   Univ New S Wales
  • 被引频次:   718
  • DOI:   10.1038/NNANO.2008.365
  • 出版年:   2009

▎ 摘  要

Carbon nanostructures have emerged as likely candidates for a wide range of applications, driving research into novel synthetic techniques to produce nanotubes, graphene and other carbon-based materials. Single sheets of pristine graphene have been isolated from bulk graphite in small amounts by micromechanical cleavage(1), and larger amounts of chemically modified graphene sheets have been produced by a number of approaches(2-7). Both of these techniques make use of highly oriented pyrolitic graphite as a starting material and involve labour-intensive preparations. Here, we report the direct chemical synthesis of carbon nanosheets in gram-scale quantities in a bottom-up approach based on the common laboratory reagents ethanol and sodium, which are reacted to give an intermediate solid that is then pyrolized, yielding a fused array of graphene sheets that are dispersed by mild sonication. The ability to produce bulk graphene samples from nongraphitic precursors with a scalable, low-cost approach should take us a step closer to real-world applications of graphene.