• 文献标题:   Triethanolamine modified graphene oxide for epoxy resin-based coatings: Corrosion inhibition on metal substrates
  • 文献类型:   Article
  • 作  者:   BAN CG, ZHANG K, HUANG L, YUAN Y
  • 作者关键词:   anticorrosion coating, epoxy resin, graphene oxide, triethanolamine
  • 出版物名称:   SURFACE INTERFACE ANALYSIS
  • ISSN:   0142-2421 EI 1096-9918
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1002/sia.7139 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Graphene oxide is an ideal nanofiller for epoxy resins because of its excellent mechanical properties, high thermal resistance, and abundant oxygen-containing functional groups. However, the poor dispersion of graphene oxide in epoxy resins restricts its application in corrosive environments. In this study, epoxy coating was prepared by incorporating triethanolamine (TEA)-modified graphene oxide (TEA-GO-EP). TEA acted as a modification agent for graphene oxide to improve its dispersion in epoxy and corrosion inhibitor for the underlying copper substrate. The long-term potentiodynamic polarization and electrochemical impedance spectroscopy results demonstrated the improved anti-corrosion performance of the TEA-GO-EP coatings in 3.5 wt.% NaCl aqueous solution, compared with the coatings without TEA. Moreover, the anti-corrosion mechanism was discussed in detail. The findings reported in this paper have important implications for developing new types of eco-friendly epoxy-based coatings.