▎ 摘　　要

We developed a polyurethane material has an excellent self-healing ability as well as mechanical strength. This system was achieved based on dual-crosslinked Diels-Alder (DA) covalent bonding reaction. The first cross-linking point is realized by the DA bonding of polyurethane chain. Because of grafted maleimide group, the maleimide functionalized GO (mGO) sheets can be regarded as analogous cross linker and provide the second cross-linking point in the system. We investigated and compared the effects of as-produced GO and mGO loading and maleimide functionalization on the mechanical properties and healing efficiency of composites. As a result, compared with those of the pure polyurethane and composites filled with the GO, such maleimide functionalization is found to effectively improve the compatibility between mGO and polymer matrix, increasing mechanical properties and healing efficiency of polyurethane composites. The mechanical properties and healing efficiency of polyurethane can be tuned readily by varying mGO concentration. The healing efficiencies were up to 99% for the nanocomposite containing mGO. These results confirm maleimide functionalization improved dispersion and interfacial interaction between the fillers and the polyurethane matrix. (C) 2017 Elsevier Ltd. All rights reserved.