• 文献标题:   The effects of molybdenum and reduced graphene oxide on corrosion resistance of amorphous nickel-phosphorus as bipolar plates in PEMFC environment
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   LV JL, LIANG TX, CHEN W
  • 作者关键词:   amorphou, corrosion resistance, pemfc, passive film, graphene
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   6
  • DOI:   10.1016/j.ijhydene.2016.03.104
  • 出版年:   2016

▎ 摘  要

The effects of reduced graphene oxide and molybdenum in amorphous nickel-phosphorus as bipolar plates on corrosion resistance in proton exchange membrane fuel cell environment were investigated. The amorphous nickel-phosphorus, amorphous nickel-phosphorus with molybdenum and amorphous nickel-phosphorus with reduced graphene oxide were obtained by the electrodeposition technique from a nickel sulfate bath. The electrochemical studies showed that the molybdenum in amorphous nickel-phosphorus improved corrosion resistance in typical proton exchange membrane fuel cell environment. In addition, the amorphous nickel-phosphorus with reduced graphene oxide exhibited the best corrosion resistance in typical proton exchange membrane fuel cell environment. The synergistic combination of amorphous nickel-phosphorus and reduced graphene oxide could improve corrosion resistance, which was supported further by Mott-Schottky analysis. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.