• 文献标题:   Graphene oxide-polyaniline nanocomposites for high performance supercapacitor and their optical, electrical and electrochemical properties
  • 文献类型:   Article
  • 作  者:   KONWER S
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Gargaon Coll
  • 被引频次:   14
  • DOI:   10.1007/s10854-016-4273-3
  • 出版年:   2016

▎ 摘  要

Polyaniline/Graphene oxide (PA/GO) composites were prepared by chemical polymerization of aniline with different wt% of GO under acid conditions. The synthesized samples were characterized by using Fourier transform infra red spectroscopy, ultraviolet-visible absorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and thermogravimetric analysis. It is found that the dc electrical conductivity dramatically increased to 84 S/m for PA/GO (5 wt%) composite at 150 A degrees C compared to pure PA (0.075 S/m). The PA/GO composites showed a reversible electrochemical response up to 150th repeated cycles as revealed by the cyclic voltammetry study. High specific capacitance of PA/GO composite of 543.75 F/g was obtained in the potential range from 0 to 0.50 V at 2 mA compared with 266.66 F/g for pure PA by galvanostatic charge-discharge analysis. Incorporation of GO into the polymer matrix has a pronounced effect on the electrical conductivity and electrochemical capacitance performance of PA/GO nanocomposites.