• 文献标题:   Novel silicon nanoparticles with nitrogen-doped carbon shell dispersed in nitrogen-doped graphene and CNTs hybrid electrode for lithium ion battery
  • 文献类型:   Article
  • 作  者:   TANG XF, WEN GW, ZHANG Y, WANG D, SONG Y
  • 作者关键词:   silicon, ndoping carbon, ndoping graphene, cnt, lithiumion battery
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   13
  • DOI:   10.1016/j.apsusc.2017.07.058
  • 出版年:   2017

▎ 摘  要

A Si-rGO/NCT composite, in which Si nanoparticles (SiNPs) are enwrapped with N-doped carbon and combine with N-doped graphene and CNTs as conductive matrices synthesized by simple solution-mixing and carbonization process with pyrolyzing melamine formaldehyde resin (MFR) is developed as a promising candidate anode material for lithium ion batteries (LIBs). The N-doped carbon outside SiNPs can not only improve the electrical conductivity of the composite, but also buffer the stress causing by huge volume change of SiNPs during the lithiation/delithiation process. The Si-rGO/NCT composite exhibits high specific capacity and good cycling stability (892.3 mAh g(-1) at 100 mA g(-1) up to 100 cycles), as well as improved rate capability. This approach provides a very facile route to obtain silicon-based anode materials. (C) 2017 Published by Elsevier B.V.