• 文献标题:   Ultraviolet Raman spectroscopy of graphene and transition-metal dichalcogenides
  • 文献类型:   Article
  • 作  者:   SAITO R, NUGRAHA ART, HASDEO EH, SIREGAR S, GUO HH, YANG T
  • 作者关键词:   doubleresonance raman, graphene, raman spectroscopy, transitionmetal dichalcogenide, ultraviolet spectroscopy, van hove singularity
  • 出版物名称:   PHYSICA STATUS SOLIDI BBASIC SOLID STATE PHYSICS
  • ISSN:   0370-1972 EI 1521-3951
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   5
  • DOI:   10.1002/pssb.201552201
  • 出版年:   2015

▎ 摘  要

Here, we overview Raman spectroscopy of graphene and transition- metal dichalcogenides as a function of laser excitation energy EL, especially in the ultraviolet (UV) region. The double resonance G' (or 2D) band of graphene is calculated for the laser energy range up to 7 eV. The intensity of the G' band is proportional to E-L(-1) for E-L = 5 eV. We also discuss electronic Raman spectra and the asymmetric Breit- WignerFano lineshape of the G band in graphene for UV light. Finally, transition- metal dichalcogenide materials show a strong optical absorption of the UV light at the M point at which we expect a two- dimensional van Hove singularity of density of states. The double- resonance Raman spectra for the UV light can be assigned to a combination or overtone phonons at the M point. [GRAPHICS] (C) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim