• 文献标题:   One-step preparation of single-layered graphene quantum dots for the detection of Fe3+
  • 文献类型:   Article
  • 作  者:   WANG HA, WU XX, DONG WL, LEE SL, YUAN QH, GAN W
  • 作者关键词:   singlelayered graphene quantum dot, onestep preparation, betacydodextrin, fluorescence sensing, ferric ion
  • 出版物名称:   SPECTROCHIMICA ACTA PART AMOLECULAR BIOMOLECULAR SPECTROSCOPY
  • ISSN:   1386-1425
  • 通讯作者地址:   Harbin Inst Technol Shenzhen
  • 被引频次:   2
  • DOI:   10.1016/j.saa.2019.117626
  • 出版年:   2020

▎ 摘  要

Single-layer graphene quantum dots are highly desirable while their facile and controllable preparations remain challenging. Herein, single-layered graphene quantum dots (sl-GQDs) were developed via a facile one-step hydrothermal synthesis, with citric add and beta-cyclodextrin (CD) as starting materials. The sl-GQDs decorated with CD molecules emit green fluorescence with a quantum yield of 5.34%, and exhibit a good response exclusively to ferric ions for their structural oxygenous groups. The linear range of the proposed sensor for ferric ions was found in a wide concentration range of 0-85 mu M. The detection limit is about 0.26 mu M. The sl-GQDs based sensing platform also demonstrates its feasibility in real water sample analysis with recoveries of 93.8%-101.5%. (C) 2019 Elsevier B.V. All rights reserved.