▎ 摘　　要

Graphene oxide (GO) is experiencing growing interest by synthetic organic chemists as a promoter of chemical transformations. The synergistic role of the multiple functionalities featuring the nanostructured carbon materials and their pi-domains enables the interplay of specific activation modes towards organic compounds that can explore unprecedented chemical modifications. A detailed comprehension of the mechanistic details that govern the transformations guided by GO is a not fully solved task in the field. In this direction, more sophisticated and diversified techniques are employed, providing insights towards intriguing activation modes exerted by the pi-matrix and the oxygenated/sulfonate groups decorating the functionalized nano-carbon material. The present Minireview accounts for a critical survey of the most recent developments in the area of GO-mediated organic transformations with a specific focus on mechanist aspects.