• 文献标题:   Unexpected Room Temperature Ferromagnetism of a Ball-Milled Graphene Oxide-Melamine Mixture
  • 文献类型:   Article
  • 作  者:   VASILIEV VP, KABACHKOV EN, KULIKOV AV, MANZHOS RA, MOROZOV IG, SHULGA YM
  • 作者关键词:   graphene oxide, melamine, ballmilling, electron spin resonance, room temperature ferromagnetism
  • 出版物名称:   MOLECULES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.3390/molecules27227698
  • 出版年:   2022

▎ 摘  要

Nitrogen-doped carbon nanomaterial (NDCNM) was synthesized by grinding a mixture of graphene oxide and melamine in a planetary mill with both balls and milling chamber of zirconium dioxide. In the electron spin resonance spectrum of NDCNM, a broad signal with g = 2.08 was observed in addition to a narrow signal at g = 2.0034. In the study using a vibrating-sample magnetometer, the synthesized material is presumably a ferromagnet with a coercive force of 100 Oe. The specific magnetization at 10,000 Oe is approximately 0.020 and 0.055 emu/g at room temperature and liquid nitrogen temperature, respectively.