• 文献标题:   Synthesis and Characterization of Graphene Oxide Supported Schiff Base Palladium Catalyst and Its Catalytic Performance to Suzuki Reaction
  • 文献类型:   Article
  • 作  者:   YUAN DZ, CHEN BB
  • 作者关键词:   graphene oxide, schiff base, suzuki reaction, palladium catalyst
  • 出版物名称:   CHINESE JOURNAL OF ORGANIC CHEMISTRY
  • ISSN:   0253-2786
  • 通讯作者地址:   E China Inst Technol
  • 被引频次:   6
  • DOI:   10.6023/cjoc201312022
  • 出版年:   2014

▎ 摘  要

Graphene oxide prepared by modified Hummers method was used to immobilize Shiff base palladium complex. The novel supported catalyst was characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray potoelectron sectroscopy (XPS), termogravity (TGA) and furier transform infrared spectrometer (FTIR). The supported palladium compound is an efficient catalyst for Suzuki reaction of aryl halides with phenylboronic acid to substituted trans-cinnamic acid or trans-stilbene at atmospheric condition in aqueous media, and the catalyst could be steadily dispersed in the reaction mixture. The supported catalyst still remains high activity after repeatedly five times.