▎ 摘　　要

In this paper, we report an all-optical NH3 gas sensor based on graphene/microfiber hybrid waveguide (GMHW). The study on the sensing mechanism shows that as the adsorption of NH3 modifies the conductivity of graphene and thus the effective refractive index of the GMHW, and the transmitting light along the GMHW is very sensitive to NH3 gas concentration. The wavelength shift induced by the NH3 absorption is spectrally demodulated by using a microfiber-based Mach-Zehnder interferometer (MZI). A high sensitivity of similar to 6 pm/ppm is obtained for the NH3 adsorption measurement. The resolution of such a sensor is similar to 0.3 ppm, mainly limited by the resolution of the optical spectrum analyzer used. The work of this paper may open a window for the development of novel GMHW-based gas sensors with high sensitivity, small footprint, easy fabrication and low cost. (C) 2013 Elsevier B. V. All rights reserved.