• 文献标题:   Sticking of Hydrogen on Supported and Suspended Graphene at Low Temperature
  • 文献类型:   Article
  • 作  者:   LEPETIT B, JACKSON B
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW LETTERS
  • ISSN:   0031-9007
  • 通讯作者地址:   Univ Toulouse
  • 被引频次:   20
  • DOI:   10.1103/PhysRevLett.107.236102
  • 出版年:   2011

▎ 摘  要

The physisorption of atomic hydrogen on graphene is investigated quantum mechanically using a semiempirical model for the lattice dynamics. A thermally averaged wave packet propagation describes the motion of the H atoms with respect to the membrane. Two graphene configurations, either supported on a silicone oxide substrate or suspended over a hole in the substrate, are considered. In both cases, the phonon spectrum is modified in such a way that graphene is stabilized with respect to thermal fluctuations. The sticking probabilities of hydrogen on these stabilized membranes at 10 K are high at low collision energies, and larger than on graphite.