• 文献标题:   Thiomersal photo-degradation with visible light mediated by graphene quantum dots: Indirect quantification using optical multipath mercury cold-vapor absorption spectrophotometry
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   MIRANDAANDRADES JR, KHAN S, TOLOZA CAT, ROMANI EC, FREIRE FL, AUCELIO RQ
  • 作者关键词:   thiomersal, graphene quantum dot, photodegradation, mercury, cold vapor atomic absorption spectrometry
  • 出版物名称:   SPECTROCHIMICA ACTA PART BATOMIC SPECTROSCOPY
  • ISSN:   0584-8547
  • 通讯作者地址:   Pontifical Catholic Univ Rio de Janeiro PUC Rio
  • 被引频次:   1
  • DOI:   10.1016/j.sab.2017.10.011
  • 出版年:   2017

▎ 摘  要

Thiomersal is employed as preservative in vaccines, cosmetic and pharmaceutical products due to its capacity to inhibit bacterial growth. Thiomersal contains 49.55% of mercury in its composition and its highly toxic ethylmercury degradation product has been linked to neurological disorders. The photo-degradation of thiomersal has been achieved by visible light using graphene quantum dots as catalysts. The generated mercury cold vapor (using adjusted experimental conditions) was detected by multipath atomic absorption spectrometry allowing the quantification of thiomersal at values as low as 20 ng L-1 even in complex samples as aqueous effluents of pharmaceutical industry and urine. A kinetic study (pseudo-first order with k = 0.11 min(-1)) and insights on the photo-degradation process are presented. (C) 2017 Elsevier B.V. All rights reserved.