• 文献标题:   Synthesis of LiFePO4/carbon/graphene for high-performance Li-ion battery
  • 文献类型:   Article
  • 作  者:   LIU XY, SUN L, VU NH, LINH DTH, DIEN PT, HOA LT, LIEN DT, NANG HX, DAO VD
  • 作者关键词:   lifepo4, carbon, graphene composite, comodification technology, graphene content, excellent electrochemical performance
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jelechem.2023.117205 EA FEB 2023
  • 出版年:   2023

▎ 摘  要

LiFePO4/carbon/graphene (LFP/C/G) composites were synthesized through a solvothermal method which used LFP/carbon with 15 % carbon content (LFP/C-15) as a precursor and changed graphene contents. LFP with 5 % graphene content (LFP/G-5) was synthesized by the same method. The effects of co-modification technology and graphene content on LFP/C/G performance were investigated. As the results, LFP/C/G compos-ites showed a significant improvement in electrochemical properties compared to LFP/C-15 and LFP/G-5. This is attributed to the superior electrical conductivity of graphene and the excellent conductive network formed by co-modification of graphene and carbon coating. Especially, when the graphene content of LFP/C/G is 15 %, the developed material provided the greatest initial discharge specific capacity at 186.2 mAh/g at 0.1C which exceeded the theoretical specific capacity of 170 mAh/g for LFP, and the extremely high capacity retention pro-portion of 95.2 % after 100 cycles at 0.1C. This finding is a promising technique for the improvement of LFP performance by co-modifying with graphene and carbon coating.