• 文献标题:   Bi2MoO6 Quantum Dots In Situ Grown on Reduced Graphene Oxide Layers: A Novel Electron-Rich Interface for Efficient CO2 Reduction
  • 文献类型:   Article
  • 作  者:   DAI WL, XIONG WW, YU JJ, ZHANG SQ, LI B, YANG LX, WANG TY, LUO XB, ZOU JP, LUO SL
  • 作者关键词:   bi2moo6 quantum dot, in situ growth, reduced graphene oxide, co2 reduction, electronrich interface
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Nanchang Hangkong Univ
  • 被引频次:   1
  • DOI:   10.1021/acsami.0c04730
  • 出版年:   2020

▎ 摘  要

Bi2MoO6 quantum dots (BM QDs, 5 nm in diameter) are evenly in situ grown on reduced graphene oxide (rGO) layers, sensitizing the graphene with high visible light response and activity for efficient solar light-driven CO2 reduction. Under irradiation, small-sized BM QDs generate active electrons and donate them to the rGO layers. Since the formation of BM QDs and the reduction of GO are undergone simultaneously, a close connection between BM QDs and rGO enables the electron injection from excited Bi2MoO6 QDs to graphene scaffolds, and abundant electrons accommodated by the rGO layers offer an electron-rich interface for CO2 reduction. With the benefit of the improved electron extraction and transport over the BM QDs/rGO interface, 84.8 mu mol g(-1) of methanol and 57.5 mu mol g(-1) of ethanol are achieved on BM QDs/rGO in 4 h with optimal composition. The total output of alcohols over BM/rGO (142.3 mu mol g(-1)) is 2.2 and 4.4 times that achieved on unmodified Bi2MoO6 QDs (64.0 mu mol g(-1)) and flower-like Bi2MoO6 (32.2 mu mol g(-1)), respectively.