• 文献标题:   Reduced graphene oxide/silica nanocomposite-reinforced anticorrosive fluorocarbon coating
  • 文献类型:   Article
  • 作  者:   ZHONG BJ, SHEN LM, ZHANG XY, LI C, BAO NZ
  • 作者关键词:   coating, electrochemistry, graphene fullerene, nanotube, surfaces interface
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Nanjing Tech Univ
  • 被引频次:   0
  • DOI:   10.1002/app.49689 EA AUG 2020
  • 出版年:   2021

▎ 摘  要

Reduced graphene oxide-silica (rGO/SiO2) nanocomposite filler was prepared with a ball milling process and then modified using a coupling agent of NH2C3H6Si(OC2H5)(3)(KH-550) to improve its dispersion in the fluoroethylene vinyl ether (FEVE) coating. The surface properties and morphologies of the modified rGO/SiO2(M-rGO/SiO2) nanocomposite filler and M-rGO/SiO2-reinforced FEVE coating were characterized by using Fourier transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). Electrochemical impedance spectroscopy (EIS) and Tafel polarization curves were applied to illustrate the corrosion resistance of the coating. The results showed that the M-rGO/SiO(2)composite can disperse well in the coating and efficiently extend the corrosion path, enhancing the anti-corrosion property of the FEVE coating. Therefore, the |Z|(0.01 Hz)of M-rGO/SiO(2)reinforced FEVE coating maintained at around 10(10) omega center dot cm(2)in the 30 days test cycle and a protection efficiency of up to 95.18% was achieved.