• 文献标题:   Adsorption of dichromate ions from aqueous solution onto magnetic graphene oxide modified by beta-cyclodextrin
  • 文献类型:   Article
  • 作  者:   WANG GH, LUO QY, DAI JL, DENG NS
  • 作者关键词:   graphene oxide, betacyclodextrin, ferroferric oxide, dichromate anion
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:   East China Univ Technol
  • 被引频次:   1
  • DOI:   10.1007/s11356-020-09389-6 EA MAY 2020
  • 出版年:   2020

▎ 摘  要

In this work, the beta-cyclodextrin modified magnetic graphene oxide (beta-CD/MGO) composite was fabricated by the in situ co-precipitation method and characterized by Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), vibrating sample magnetometer (VSM), and particle size analysis. The adsorption behavior of dichromate ions on the beta-CD/MGO was investigated, and the mechanism of adsorption was also studied using FT-IR and XPS. The results from SEM and TEM showed that the graphene oxide (GO) layer became rough, and many fine particles were attached after compounding with ferroferric oxide and beta-cyclodextrin. The characterization results of FT-IR and XPS show that that beta-cyclodextrin and ferroferric oxide have been perfectly compounded to the graphene oxide layer and beta-CD/MGO has a particle size of about 460 nm, a specific surface area of 252.3 m(2)g(-1), and a saturation magnetization of 73.5 emu g(-1). The adsorption amount of dichromate ions on the beta-CD/MGO is affected by pH, adsorbent dosage, and adsorption time. Kinetic studies showed that the adsorption process followed a pseudo-second-order kinetic model. Equilibrium data agreed very well with the Langmuir model, the maximum adsorption amount of dichromate ions on the beta-CD/MGO was 49.95 mg g(-1). After five successive adsorbent reuses, the reuse rate is still 73%, indicating the excellent potential reusability of beta-CD/MGO adsorbent. beta-CD/MGO exhibits excellent adsorption performance for dichromate ions. As an environmentally friendly magnetic adsorbent, beta-CD/MGO is suitable for the treatment of dichromate-containing wastewater.