• 文献标题:   A thin slice-like Co3O4/N-doped graphene hybrid as an efficient catalyst for oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   WU J, WANG JX, LV Y, WANG XB
  • 作者关键词:   ndoped graphene, oxygen reduction reaction, slicelike co3o4, electrocatalyst
  • 出版物名称:   INORGANIC CHEMISTRY COMMUNICATIONS
  • ISSN:   1387-7003 EI 1879-0259
  • 通讯作者地址:   Hubei Univ
  • 被引频次:   3
  • DOI:   10.1016/j.inoche.2019.06.005
  • 出版年:   2019

▎ 摘  要

A thin slice-like Co3O4/N-doped graphene (Co3O4-N-Gr) was prepared through a hydrothermal reaction. The asprepared Co3O4-N-Gr displayed an onset potential and half-wave potential of 0.98 and 0.86 V, which were 40 and 80 mV larger than that of Pt/C (0.94 and 0.78 V), while its Tafel slope (31.4 mV dec(-1)) was much lower than Pt/C (44.7 mV dec(-1)). Moreover, the current density retained 96.25% after working for 6000 s and had no change after adding methanol. These suggest that the Co3O4-N-Gr is promising as an efficient electrocatalyst for oxygen reduction reaction (ORR) in alkaline medium when compared with Pt/C and other reported non-precious catalysts.