• 文献标题:   Graphene oxide grafted with Pd17Se15 nano-particles generated from a single source precursor as a recyclable and efficient catalyst for C-O coupling in O-arylation at room temperature
  • 文献类型:   Article
  • 作  者:   JOSHI H, SHARMA KN, SHARMA AK, PRAKASH O, SINGH AK
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Indian Inst Technol Delhi
  • 被引频次:   39
  • DOI:   10.1039/c3cc42608d
  • 出版年:   2013

▎ 摘  要

The Pd17Se15 nanoparticles, synthesized for the first time from a single source precursor [Pd(L)Cl-2]{L = 1,3-bis(phenylselenyl)propan-2-ol} and grafted onto graphene oxide, show high catalytic activity in C-O coupling between aryl/heteroaryl chlorides/bromides and phenol at room temperature (Pd loading 1 mol%; yield up to 94%).