• 文献标题:   Strategies to improve the adsorption properties of graphene-based adsorbent towards heavy metal ions and their compound pollutants: A review
  • 文献类型:   Review
  • 作  者:   KONG QP, SHI XQ, MA WW, ZHANG FZ, YU T, ZHAO F, ZHAO DD, WEI CH
  • 作者关键词:   graphenebased adsorbent, heavy metal, surface functionalization regulation, morphology structure control, material composite
  • 出版物名称:   JOURNAL OF HAZARDOUS MATERIALS
  • ISSN:   0304-3894 EI 1873-3336
  • 通讯作者地址:  
  • 被引频次:   82
  • DOI:   10.1016/j.jhazmat.2021.125690 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

Heavy metal-containing wastewater can be treated by adsorption technology to obtain ultra-low concentration or high-quality treated effluent. Due to the constraints of the specific surface area, surface electrical structure and spatial effect of conventional adsorbents, it is often difficult to obtain adsorbents within high adsorption capacity. Graphene has characteristics of large specific surface area, small particle size, and high adsorption efficiency. It is considered as one of the research hotspots in recent years. However, despite graphene's unique properties, graphene-based adsorbents still have some drawbacks, i.e. graphene nanosheets are easier to be stacked with each other via pi-pi stacking and van der Waals interactions, which affect the site exposure, impede the rapid mass transport and limit its adsorption performance. Special strategy is needed to overcome its drawbacks. This work summarizes recent literatures on utilization of three strategies-surface functionalization regulation, morphology and structure control and material composite, to improve the adsorption properties of graphene-based adsorbent towards heavy metal removal. A brief summary, perspective on strategies to improving adsorption properties of graphene-based materials for heavy metal adsorption are also presented. Certainly, this review will be useful for designing and manufacturing of graphene-based nanomaterials for water treatment.