• 文献标题:   Synthesis of a Sn-In mixed oxide/graphene hybrid as an electrode material with improved Li-storage properties
  • 文献类型:   Article
  • 作  者:   XING WY, WANG X, SONG L, LI SR, CHEN CH, HU Y
  • 作者关键词:   composite material, nanostructure, electrochemical propertie, precipitation
  • 出版物名称:   MATERIALS CHEMISTRY PHYSICS
  • ISSN:   0254-0584
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   4
  • DOI:   10.1016/j.matchemphys.2013.03.017
  • 出版年:   2013

▎ 摘  要

Mixing of aqueous suspensions of indium chloride, tin chloride and graphene oxide leads to the instantaneous precipitation of a hybrid material followed by the calcination under inert atmosphere at 450 degrees C results in Sn-In mixed oxide nanoparticles deposited on graphene sheets. This hybrid material is characterized by X-ray diffraction, X-ray photoelectron spectroscopy, atomic force microscopy and transmission electron microscopy. The Sn-In mixed oxide nanoparticles with the diameter of similar to 10 nm are uniformly attached onto the surface of graphene. The Sn-In mixed oxide/graphene (Sn-In/G) hybrids exhibit superior Li-storage properties over graphene and bare Sn-In mixed oxide, and the optimum molar ratio of Sn-In mixed oxide/graphene is 1:1. With the Sn-In mixed oxide/graphene mass ratio of 1:1, the hybrid exhibits high cyclic stability and capacity retention, where 708 mA h g(-1) and 570 mA h g(-1) could still be obtained after 10 and 30 cycles, indicating potential application in electrode materials for lithium ion batteries. (C) 2013 Published by Elsevier B.V.