• 文献标题:   Highly Active Platinum Nanoparticles on Graphene Nanosheets with a Significant Improvement in Stability and CO Tolerance
  • 文献类型:   Article
  • 作  者:   HE DP, CHENG K, LI HG, PENG T, XU F, MU SC, PAN M
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   83
  • DOI:   10.1021/la2045493
  • 出版年:   2012

▎ 摘  要

Graphene nanosheets (GNS) supporting Pt nanoparticles (PNs) are prepared using perfluorosulfonic acid (PFSA) as a functionalization and anchoring agent. Transmission electron microscope (TEM) results indicate that the prepared Pt NPs are uniformly deposited on GNS with a narrow particle size ranging from I to 4 nm in diameter. A high catalytic activity of this novel catalyst is observed by both cyclic voltammetry and oxygen reduction reaction (ORR) measurements due to the increasing of proton (H+) transmission channels. Significantly, this novel PFSA-functionalized Pt/GNS (PFSA-Pt/GNS) catalyst reveals a better CO oxidation and lower loss rate of electrochemical active area in comparison with that of the plain Pt/GNS and conventional Pt/C catalysts, indicating our PFSA-Pt/GNS catalysts hold much higher stability and CO tolerance by virtue of introduction of PFSA.