• 文献标题:   Fabrication of reduced graphene oxide-BiOCl hybrid material via a novel benzyl alcohol route and its enhanced photocatalytic activity
  • 文献类型:   Article
  • 作  者:   TIAN LH, LIU JY, GONG CQ, YE LQ, ZAN L
  • 作者关键词:   reduced graphene oxide, biocl, photocatalytic, photosensitizer, electron transfer
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Wuhan Univ
  • 被引频次:   23
  • DOI:   10.1007/s11051-013-1917-6
  • 出版年:   2013

▎ 摘  要

Reduced graphene oxide (RGO)-BiOCl hybrid materials were prepared by a novel benzyl alcohol route. The formation of uniform RGO-BiOCl hybrids was attributed to the interaction of introduced graphene oxide and BiOCl, which resulted in a selective growth of BiOCl along (110) orientation. The RGO-BiOCl hybrids showed both enhanced visible-light and ultraviolet light photocatalytic activities compared to nano-BiOCl with similar particle size. In particular, the first-order kinetic constant (k) of Rhodamine B on the optimal RGO (0.73 %)-BiOCl hybrid was 2.5 times that on bare nano-BiOCl under visible-light irradiation. For RGO-BiOCl hybrids, RGO probably acted as a photosensitizer in photocatalytic reaction and resulted in the improved visible-light photocatalytic performance. However, RGO was an excellent electron transfer and inhibited the recombination of electron-hole pairs on BiOCl under ultraviolet light.