• 文献标题:   Synthesis of akageneite (beta-FeOOH)/reduced graphene oxide nanocomposites for oxidative decomposition of 2-chlorophenol by Fenton-like reaction
  • 文献类型:   Article
  • 作  者:   XIAO F, LI WT, FANG LP, WANG DS
  • 作者关键词:   betafeooh, fentonlike reaction, heterogeneous degradation, rgo, 2chlorophenol
  • 出版物名称:   JOURNAL OF HAZARDOUS MATERIALS
  • ISSN:   0304-3894 EI 1873-3336
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   45
  • DOI:   10.1016/j.jhazmat.2016.01.011
  • 出版年:   2016

▎ 摘  要

In this work, the composite of reduced graphene oxide and akageneite (Ak/rGO) was synthesised by co-precipitating and reduction processes. The morphological and structural features of the synthesized composites (Ak/rGO) were characterized by XRD, SEM, BET, FTIR, Zeta potential and XPS. The results revealed that (1) beta-FeOOH was successfully loaded on the reduced graphene oxide (rGO); (2) the presence of strong interfacial interactions (Fe-O-C bonds) between rGO and beta-FeOOH was observed; (3) the reduction of graphene oxide may be inhabited in the formation process of beta-FeOOH, producing rGO sheets rather than rGO sphere. In the heterogeneous Fenton-like reaction, the degradation rate constants of 2-chlorophenol (2-CP) increased 2-5 times after the addition of rGO probably due to the Fe-O-C bond. The increase of the content of rGO could contribute to the removal of 2-CP, due to the synergy of catalysis and 2-CP adsorption towards Ak/rGO. In this study, the Ak/rGO composite has exhibited great potential and significant prospects for environmental application. (C) 2016 Elsevier B.V. All rights reserved.