▎ 摘　　要

The development and utilization of high-performance Pt-alternative anode materials with acceptable costs have recently become a hot issue in the fuel cell field. Here, we put forward a convenient and cost-effective scalable method to the bottom-up construction of an ultrafine Rh nanoparticle-decorated three-dimensional (3D) porous boron and nitrogen dual-doped graphene (Rh/BN-G) architecture via a convenient self-assembly process. Such a 3D porous hybrid structure can not only facilitate the transport of external electrolytes into the innermost catalyst surface but also create a large number of catalytically active sites in the catalytic system. Consequently, the newly developed 3D Rh/BN-G architecture manifests unusual electrocatalytic abilities toward methanol oxidation reaction, including a large electrochemically active surface area, high mass/specific activities, and superior long-term stability, all of which are much better than those of the reference Rh/carbon black, Rh/carbon nanotube, and Rh/undoped graphene catalysts.