• 文献标题:   Adsorption and Reaction of PbPc on Hydrogenated Epitaxial Graphene
  • 文献类型:   Article
  • 作  者:   SLAWIG D, GRUSCHWITZ M, GERSTMANN U, RAULS E, TEGENKAMP C
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1021/acs.jpcc.1c06320 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

We study the interplay of chemisorbed hydrogen and physisorbed PbPc molecules on epitaxial graphene by means of surface transport and density functional theory. While the adsorption of atomic hydrogen induces strong localization by local sp(3) rehybridization of the graphene lattice, PbPc is not affecting the transport properties of clean graphene. Moreover, on hydrogenated graphene, PbPc is selectively lifting the lattice distortion, while binding the atomic hydrogen and recovering the conductivity of the pristine graphene. Our results show that graphene is a multipurpose template for sensing both chemisorbed and physisorbed species and the implementation of a chemical selectivity.