• 文献标题:   Characterization and properties of in situ emulsion polymerized poly(methyl methacrylate)/graphene nanocomposites
  • 文献类型:   Article
  • 作  者:   KUILA T, BOSE S, KHANRA P, KIM NH, RHEE KY, LEE JH
  • 作者关键词:   graphene, mechanical propertie, thermal analysi, electrical propertie
  • 出版物名称:   COMPOSITES PART AAPPLIED SCIENCE MANUFACTURING
  • ISSN:   1359-835X
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   115
  • DOI:   10.1016/j.compositesa.2011.08.014
  • 出版年:   2011

▎ 摘  要

Poly(methyl methacrylate) (PMMA)/graphene nanocomposites were prepared by in situ emulsion polymerization. Raman and Fourier transform infrared spectra showed that PMMA polymer contained partially reduced graphite oxide. Dynamic mechanical analysis and differential scanning calorimetry analysis showed that graphene in the PMMA matrix acted as reinforcing filler; it enhanced the storage moduli and glass transition temperatures of the nanocomposites. Thermogravimetric analysis showed that the thermal stability of the nanocomposites increased by ca. 35 degrees C. The electrical conductivity of nanocomposite with 3 wt.% graphite oxide was 1.5 S m(-1) at room temperature. (C) 2011 Elsevier Ltd. All rights reserved.