• 文献标题:   Hydrothermal synthesis of simonkolleite microplatelets on nickel foam-graphene for electrochemical supercapacitors
  • 文献类型:   Article
  • 作  者:   KHAMLICH S, BELLO A, FABIANE M, NGOM BD, MANYALA N
  • 作者关键词:   graphene, composite structure, simonkolleite, supercapacitor
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Univ Pretoria
  • 被引频次:   19
  • DOI:   10.1007/s10008-013-2206-0
  • 出版年:   2013

▎ 摘  要

Nickel foam-graphene (NF-G) was synthesized by chemical vapour deposition followed by facial in situ aqueous chemical growth of simonkolleite (Zn-5(OH)(8)Cl-2 center dot H2O) under hydrothermal conditions to form NF-G/simonkolleite composite. X-ray diffraction and Raman spectroscopy show the presence of simonkolleite on the NF-G, while scanning and transmission electron microscopies show simonkolleite micro-plates like structure evenly distributed on the NF-G. Electrochemical measurements of the composite electrode give a specific capacitance of 350 Fg(-1) at current density of 0.7 Ag-1 for our device measured in three-electrode configuration. The composite also shows a rate capability of similar to 87 % capacitance retention at a high current density of 5 Ag-1, which makes it a promising candidate as an electrode material for supercapacitor applications.